PREPARATION OF CHITOSAN GRAFT COPOLYMERS AND STUDY OF THEIR WATER-SWELLING PROPERTIES

Autor: A. D. Moroz, S. S. Dryabina, M. A. Vaniev, Zh. N. Malysheva, I. A. Novakov
Rok vydání: 2021
Předmět:
Zdroj: IZVESTIA VOLGOGRAD STATE TECHNICAL UNIVERSITY. :83-90
ISSN: 1990-5297
DOI: 10.35211/1990-5297-2021-12-259-83-90
Popis: In this work, graft copolymers of chitosan with trimethylmethacryloxyethylammonium methyl sulfate were synthesized by the method of controlled radical polymerization, and it was found that replacing the dimethylformamide aprotic solvent with water increases the degree of grafting. With the aim of the possible use of chitosan copolymers as a functional component for regulating the water-swelling properties of elastomers, the kinetics of swelling of the samples was investigated. An increase in the degree of swelling of the copolymers in comparison with the initial chitosan was revealed, and the influence of the molecular weight and the conditions of their synthesis was established.
Databáze: OpenAIRE