Formation of a Mn(IV) Species in the Reaction Mixture of a Manganese(II) Complex and an Aliphatic Aldehyde

Autor:	Yuichi Sutoh, Yuzo Nishida
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Benzimidazole Inorganic chemistry chemistry.chemical_element Scrapie Manganese medicine.disease Medicinal chemistry Copper Oxygen Aldehyde Inorganic Chemistry Esr spectra chemistry.chemical_compound chemistry Manganism medicine Physical and Theoretical Chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 35:575-577
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533170500199075
Popis:	ESR spectra showed that manganese(II) complexes with tripodal‐ligands containing a benzimidazole group can activate oxygen easily in the presence of an aliphatic aldehyde leading to the conversion of the Mn(II) species to a Mn(IV) species. The above facts may give important information to elucidate the origin of the so‐called “manganism,” a dreaded illness marked by Parkinson's‐like tremors, and also give possible reasons as to why the soil in certain regions of Iceland, Slovakia, and Colorado where scrapie, Creutzfeldt‐Jacob disease, and chronic wasting disease clusters are found, is low in copper and high in manganese.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::91e36dd777a679430cc61f1b3c433738 https://doi.org/10.1080/15533170500199075 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.