Crystal structure of the copper(II) ternary complex of N-salicylidene-l-serinato with 2,6-diaminopyridine

Autor:	Ignasi Mata, José A. Castro, Juan J. Fiol, Adela López-Zafra, Araceli Cabrero, Elies Molins, Angel García-Raso
Rok vydání:	2003
Předmět:	Schiff base Coordination sphere Ligand chemistry.chemical_element Crystal structure Copper Square pyramidal molecular geometry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Ternary operation Ternary complex
Zdroj:	Polyhedron. 22:403-409
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(02)01364-5
Popis:	The ternary [Cu(Sal-( l -Ser))(2,6-diaminopyridine)H2O] (1b) complex has been prepared and the crystal structure determined. The copper(II) cation has a square pyramidal geometry, being coordinated to the tridentate Sal-( l -Ser) Schiff base ligand and the heterocyclic nitrogen atom N(11) of the 2,6-diaminopyridine molecule which occupying the corners of the square base. The coordination sphere about the copper is completed by an axial O(W) atom of a water molecule. Spectroscopic data are discussed. Preliminary toxicity studies [larva-to-adult viability (V) and developmental time (in days) (DT)] of several copper(II) compounds including complex 1 and other related previously described complexes [Cu(Sal-( l -Ser))H2O]·H2O (2) and [Cu(Sal-Ser)(2-aminopyridine)] (3) against Drosophila melanogaster (Or-R) show that these copper(II) complexes display less toxicity than simple copper(II) salts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::91e1a25550e95d6675021f939d512640 https://doi.org/10.1016/s0277-5387(02)01364-5 Zobrazit plný text záznamu Full Text from ScienceDirect