Azide-assisted terminal crosslinking of ionomeric blocks: Effects on morphology and proton conductivity

Autor:	Jeong-Mo Hwang, Tae-Hyun Kim, Roshni Lilly Thankamony
Rok vydání:	2012
Předmět:	Materials science Arylene Filtration and Separation Ether Conductivity Thermal conduction Biochemistry Sulfone chemistry.chemical_compound Membrane chemistry Polymer chemistry Copolymer General Materials Science Azide Physical and Theoretical Chemistry
Zdroj:	Journal of Membrane Science. :58-65
ISSN:	0376-7388
DOI:	10.1016/j.memsci.2011.12.002
Popis:	A novel terminally crosslinked block SPES-b membrane was prepared using an azide-assisted thermal curing of sulfonated multiblock poly(arylene ether sulfone). The membrane morphologies and conductivities were investigated as a function of temperature. The crosslinked block SPES-b membrane showed higher proton conductivities than Nafion® both at 20 °C (0.09 S/cm) and 100 °C (0.77 S/cm). High temperatures induced significant conduction enhancements and morphological changes for SPES-b.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::91dfbe0f0656fab19e887ece3265de14 https://doi.org/10.1016/j.memsci.2011.12.002 Zobrazit plný text záznamu Full Text from ScienceDirect