Enhanced lithium ions storage performance of Fe2(SO4)3 anode material synthesized by solution calcination route with the assistance of melamine
| Autor: | Jinhuan Yao, Jiqiong Jiang, Yanwei Li, Xiuying Jin, Tengfei Jin |
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| Rok vydání: | 2022 |
| Předmět: |
Electrode material
Materials science Mechanical Engineering Diffusion chemistry.chemical_element High capacity Condensed Matter Physics law.invention Ion Anode chemistry.chemical_compound Chemical engineering chemistry Mechanics of Materials law General Materials Science Calcination Lithium Melamine |
| Zdroj: | Materials Letters. 307:131101 |
| ISSN: | 0167-577X |
| Popis: | Exploring novel electrode materials with high capacity, good cyclability, and low cost is very crucial for the development of lithium-ion batteries (LIBs). Herein, Fe2(SO4)3 anode material is synthesized by a facile solution calcination route with the assistance of melamine. The Fe2(SO4)3 sample synthesized with the assistance of melamine exhibits much superior high-rate capability (with a reversible capacity of 621 mA h g−1 at 5.0 A g−1) and long-term cyclability (maintaining a reversible capacity of 755 mA h g−1 after 600 cycles at 1.0 A g−1). Moreover, the Fe2(SO4)3 sample displays significant pseudocapacitive behavior during the discharge/charge processes; the lithium ions diffusion coefficient is evaluated to be in the range of 10−11 ∼ 10−13 cm2 s−1. |
| Databáze: | OpenAIRE |
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