Ethyl 3,3-diamino-2-(2-p-tolylpyrimidin-4-yl)acrylate, a new representative of hetarylketene aminals

Autor: V. A. Dorokhov, V. S. Bogdanov, M. A. Present
Rok vydání: 1994
Předmět:
Zdroj: Russian Chemical Bulletin. 43:1550-1552
ISSN: 1573-9171
1066-5285
DOI: 10.1007/bf00697147
Popis: A new representative of hetarylketene aminals, ethyl 3,3-diamino-2-(2-p-tolylpyrimidin-4-yl)acrylate, was synthesized by the reaction ofp-toluamidine with the condensation product of dimethylformamide dimethyl acetal and the difluoroboron chelate of acetyl(ethoxycarbonyl)ketene (N-benzoyl)aminal. This synthesis is an example of pyrimidine ring assembly using the methodology based on transformations of chelate complexes.
Databáze: OpenAIRE