Cage effect on the photolysis of chlorine in solution

Autor:	K. Brady Clark, David Griller
Rok vydání:	1990
Předmět:	Photodissociation Analytical chemistry General Physics and Astronomy Photoacoustic imaging in biomedicine Quantum yield chemistry.chemical_element Calorimetry Photochemistry Wavelength chemistry Chlorine Cage effect Physical and Theoretical Chemistry Excess energy
Zdroj:	Chemical Physics Letters. 168:477-481
ISSN:	0009-2614
DOI:	10.1016/0009-2614(90)85147-5
Popis:	The photodissociation quantum yield of chlorine in CCl 4 was determined at 308 and 337 nm using the technique of laser-induced photoacoustic calorimetry (PAC). The quantum yield for photodissociation was observed to be wavelength dependent (0.16 and 0.22 at 337 and 308 nm, respectively). This wavelength dependence originates in the excess energy that is delivered to the geminate radical pair.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9156a70d6d3c4432de121b5041349849 https://doi.org/10.1016/0009-2614(90)85147-5 Zobrazit plný text záznamu