Elemental fluorine. Part 4. Use of elemental fluorine for the halogenation of aromatics

Autor:	John S. Moilliet, Richard D. Chambers, Christopher John Skinner, Malcolm J. Atherton
Rok vydání:	1996
Předmět:	Nitrobenzene Inert chemistry.chemical_compound chemistry Inorganic chemistry Fluorine chemistry.chemical_element Halogenation Organic chemistry Substrate (chemistry) Sulfuric acid Iodine
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :1659
ISSN:	1364-5463 0300-922X
Popis:	New methodolgy for direct iodination of benzenoid compounds has been developed; the aromatic substrate is simply mixed with iodine and sulfuric acid, suspended in an inert medium, such as 1,1,2-trichlorotrifluoroethane (CF2CICFCl2) or perfluorocarbon, and elemental fluorine is passed through the system at room temperature. High conversions to iodoaromatic products occur, even with some deactivated systems, e.g. nitrobenzene. A very powerful brominating system is produced using the analagous methodology.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9152df42f9f49a5e4064fa39eee03683 https://doi.org/10.1039/p19960001659 Zobrazit plný text záznamu