Intramolecular aldol condensation of Michael adducts of levoglucosenone and cyclododecanone

Autor:	Liliya Kh. Faizullina, Yuliya A. Khalilova, Farid A. Valeev
Rok vydání:	2021
Předmět:	Chemistry Intramolecular force Diastereomer Organic chemistry Aldol condensation General Chemistry Adduct Cyclododecanone
Zdroj:	Mendeleev Communications. 31:493-494
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2021.07.018
Popis:	Base-promoted intramolecular aldol condensation of diastereomeric Michael adducts of levoglucosenone and cyclododecanone affords 12-hydroxy-14,20-dioxatetra-cyclo[9.6.1.112,17.113,16]icosan-18-one as a mixture of three diastereomers. The products thus obtained are promising for synthesizing 14-membered macrocyclic compounds, including cembranoids and their analogues.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::914280bdf468b59878dc4dc6907557f9 https://doi.org/10.1016/j.mencom.2021.07.018 Zobrazit plný text záznamu Full Text from ScienceDirect