C,C′-Ru to C,B′-Ru isomerisation in bis(phosphine)Ru complexes of [1,1′-bis(ortho-carborane)]
| Autor: | Rebekah J. Jeans, Alan J. Welch, Georgina M. Rosair |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
Ligand
Metals and Alloys General Chemistry Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Carborane Molecule Reactivity (chemistry) Isomerization Phosphine |
| Zdroj: | Chemical Communications. 58:64-67 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d1cc06119d |
| Popis: | We report herein the first example of the controlled isomerisation of a C,Cʹ-bound (to metal) bis(ortho-carborane) ligand to C,Bʹ-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned. |
| Databáze: | OpenAIRE |
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