Exact mass determination and computing of the elemental composition of chemical compounds in complex mixtures separated by glass capillary columns

Autor:	U. Schröder, S. Meier, H. Elmenhorst, U. Rapp
Rok vydání:	1975
Předmět:	Mass Elemental composition Chromatography Capillary column Capillary action Chemistry Organic Chemistry Clinical Biochemistry Analytical chemistry Separator (oil production) Mass spectrometry Biochemistry Analytical Chemistry
Zdroj:	Chromatographia. 8:474-478
ISSN:	1612-1112 0009-5893
DOI:	10.1007/bf02267586
Popis:	A fraction of tobacco smoke condensate has been separated by GC-MS analysis on glass capillary columns. The capillary column is coupled directly to the mass spectrometer, omitting the carrier gas separator. A technique is described which allows the determination of the exact masses even on minor GC peaks which contain 1–2 ng of the chemical compound. The elemental composition can be computed from these exact masses. The determination of the exact masses is done with the aid of a data system. The error in the determination is less than 3 millimass units. The resolution of the double focussing mass spectrometer was 3000, cyclic scanning was done with 3 s/decade.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9138a6669f3db580302e1c38d7c8f9d2 https://doi.org/10.1007/bf02267586 Zobrazit plný text záznamu Full text from SpringerLink