Hybrid nanocomposites based on poly aryl ether ketone, boron carbide and multi walled carbon nanotubes: evaluation of tensile, dynamic mechanical and thermal degradation properties
Autor: | Rebbapragada Subba Rao, Karingamanna Jayanarayanan, Manu Remanan, Shantanu Bhowmik, Lalit Varshney, Mathew Abraham |
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Rok vydání: | 2016 |
Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Ketone Materials science Nanocomposite Polymers and Plastics General Chemical Engineering Aryl Ether 02 engineering and technology Carbon nanotube Boron carbide 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention chemistry.chemical_compound chemistry law Ultimate tensile strength Physical and Theoretical Chemistry Composite material 0210 nano-technology |
Zdroj: | e-Polymers. 16:493-503 |
ISSN: | 1618-7229 2197-4586 |
Popis: | In this study an attempt has been made to incorporate a radiation resistant filler like boron carbide (B4C) nanopowder along with multi walled carbon nanotubes (MWCNT) in a high performance polymer namely poly aryl ether ketone (PAEK) for potential applications in the nuclear industry. The dispersion of nanofillers in PAEK was established by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Infra red (IR) spectroscopy indicated the interaction between functionalized MWCNT (F-MWCNT) and PAEK. The optimum combination of B4C and F-MWCNT was obtained from the tensile property analysis. It was found from the dynamic mechanical analysis that the storage modulus of the composite at elevated temperature was enhanced by B4C inclusions. Mechanical damping factor spectra showed the shift of PAEK glass transition temperature to higher values due to the presence of B4C and F-MWCNT. Thermogravimetric analysis (TGA) presented the resistance offered by B4C to the degradation of PAEK especially at elevated temperatures. |
Databáze: | OpenAIRE |
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