Investigation of manufacturing parameters for NaCl–Ni granule type cathodes used in low temperature NaSICON sodium-metal chloride batteries
| Autor: | Sang Ook Kang, Sai Bhavaraju, Jeongsoo Kim, Seung Hwan Jo, Jong-Seon Kim |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Materials science
Kinetics 02 engineering and technology 010402 general chemistry Electrochemistry 01 natural sciences Chloride law.invention Metal chemistry.chemical_compound Sodium chloroaluminate law Materials Chemistry Fast ion conductor medicine Mechanical Engineering Granule (cell biology) Metals and Alloys 021001 nanoscience & nanotechnology Cathode 0104 chemical sciences Chemical engineering chemistry Mechanics of Materials visual_art visual_art.visual_art_medium 0210 nano-technology medicine.drug |
| Zdroj: | Journal of Alloys and Compounds. 665:288-293 |
| ISSN: | 0925-8388 |
| DOI: | 10.1016/j.jallcom.2016.01.001 |
| Popis: | In this work, the optimum manufacturing condition was investigated for the granule-type cathodes used in low temperature sodium-metal chloride batteries using NaSICON (Na1+xZr2SixP3-xO12) solid electrolytes. The granule-type cathodes with different shapes, pore sizes and tap densities were obtained by controlling operation parameters of granulator such as roll speed and pressure. From standard cell tests at 195 °C using four granule-type cathodes, the optimum roll speed (1.5 rpm) was sorted to produce stable granule-type cathodes for efficient electrochemical performance. From the characterization of granules and the battery tests, it was revealed that the polygon-type granules (A, C) produced at an adequate roll speed (1.5 rpm) enable favorable battery performances even at high current density of 50 mA/cm2 for 200 cycles. The main advantages of A and C granule-type cathodes seem to come from the stable metal connection among the granules that attribute to the favorable morphology (polygon) and homogenous green compacts. The relatively more efficient cathode kinetics were observed for the A sample manufactured at higher roll pressure (10 MPa) compared with the C sample (1.2 MPa), which supported the importance of roll pressure in optimizing the microscopic properties inside the granules (pore size distribution, green density, metal connectivity, etc.) for positive cathode kinetics. |
| Databáze: | OpenAIRE |
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