Strategy towards large two-photon absorption cross-sections for diketopyrrolopyrroles

Autor: Akihiro Ando, Anna Purc, Daniel T. Gryko, Krzysztof Sobczyk, Kenji Kamada, Yusuke Sakagami
Rok vydání: 2015
Předmět:
Zdroj: Journal of Materials Chemistry C. 3:742-749
ISSN: 2050-7534
2050-7526
DOI: 10.1039/c4tc02375g
Popis: Three quadrupolar donor–acceptor–donor compounds bearing diketopyrrolopyrroles as a central core and exceptionally electron-rich diarylaminofurans and dialkylaminobenzofuran as donors were designed. Straightforward synthesis afforded these dyes in good overall yield. These donor–acceptor–donor systems turned out to be strong red-emitters with fluorescence extending well into the NIR region. Two-photon brightness (850–1900 GM) was found to be larger than for any previously studied diketopyrrolopyrrole dyes.
Databáze: OpenAIRE