Strategy towards large two-photon absorption cross-sections for diketopyrrolopyrroles
Autor: | Akihiro Ando, Anna Purc, Daniel T. Gryko, Krzysztof Sobczyk, Kenji Kamada, Yusuke Sakagami |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Journal of Materials Chemistry C. 3:742-749 |
ISSN: | 2050-7534 2050-7526 |
DOI: | 10.1039/c4tc02375g |
Popis: | Three quadrupolar donor–acceptor–donor compounds bearing diketopyrrolopyrroles as a central core and exceptionally electron-rich diarylaminofurans and dialkylaminobenzofuran as donors were designed. Straightforward synthesis afforded these dyes in good overall yield. These donor–acceptor–donor systems turned out to be strong red-emitters with fluorescence extending well into the NIR region. Two-photon brightness (850–1900 GM) was found to be larger than for any previously studied diketopyrrolopyrrole dyes. |
Databáze: | OpenAIRE |
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