| Autor: |
Li Guang Xiao, Ya Bing Liu |
| Rok vydání: |
2014 |
| Předmět: |
|
| Zdroj: |
Advanced Materials Research. :376-379 |
| ISSN: |
1662-8985 |
| DOI: |
10.4028/www.scientific.net/amr.1004-1005.376 |
| Popis: |
A 1-D chain-like POM - based organic-inorganic hybrid compound with the chemical formula of [Ni (en)2]{[Ni (en)2]2[Mo8V8O40(VO4)]}[(NH2)2(C2H4)2NH]2·2H2O (en = ethylenediamine) (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of the bi-supported tetra-capped Keggin-type {[Ni (en)2]2[Mo8V8O40(VO4)]}2-building blocks and [Ni (en)2]2+metal organic cationic moieties are connected together to form 1-D chain through covelent-bonding interactions, which is further linked into 3-D supramolecular networks . The degradation of methylene blue (MB) under UV irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for MB degradation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
