Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye
| Autor: | Feng Mei, Chuanxiang Qin, Sonsong Tang, Zhimin Bao, Lixing Dai, Chuchu Lu, Guoqiang Chen |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Polymers and Plastics General Chemical Engineering Radical polymerization Polyacrylonitrile Cationic polymerization 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry Acryloyl chloride 01 natural sciences Fluorescence 0104 chemical sciences Disperse dye chemistry.chemical_compound chemistry Polymer chemistry Copolymer Acrylonitrile 0210 nano-technology |
| Zdroj: | Fibers and Polymers. 18:1017-1024 |
| ISSN: | 1875-0052 1229-9197 |
| DOI: | 10.1007/s12221-017-7053-7 |
| Popis: | One new polymerizable fluorescent disperse dye (PEANI) based on 1,8-naphthalimide was synthesized via reaction of 2-(2-hydroxyethyl)-6-(1-pyrrolidinyl)-1H-benzo [de]isoquinoline-1,3(2H)-dione (PAENI) with acryloyl chloride firstly. Dye’s structure and fluorescent properties were carefully investigated using nuclear magnetic resonance (1H-NMR), UV-Vis and fluorescent spectra. Then the yellow copolymer (F-PAN) of PEANI and acrylonitrile was obtained through radical polymerization. Fluorescent nanofiber membrane could be prepared by electrospinning of the F-PAN solution in N,N-dimethylformamide solvent and strong green fluorescent emission located around 510 nm could be found (λex=450 nm). The electrospun F-PAN membrane showed obvious fluorescent effect even the mass ratio of PEANI to acrylonitrile was only 0.1 %, which has broken through the traditional limitation of using the cationic dye involved in the dyeing procedure to obtain fluorescent acrylic fabrics. |
| Databáze: | OpenAIRE |
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