Analysis of the Raman spectrum of SF6
| Autor: | A. Aboumajd, H. Berger, R. Saint-Loup |
|---|---|
| Rok vydání: | 1979 |
| Předmět: |
Materials science
Infrared Overtone Anharmonicity Resolution (electron density) Fundamental frequency Atomic and Molecular Physics and Optics symbols.namesake Nuclear magnetic resonance Raman band symbols Coherent anti-Stokes Raman spectroscopy Physical and Theoretical Chemistry Atomic physics Raman spectroscopy Spectroscopy |
| Zdroj: | Journal of Molecular Spectroscopy. 78:486-492 |
| ISSN: | 0022-2852 |
| DOI: | 10.1016/0022-2852(79)90073-0 |
| Popis: | The Raman active fundamentals ν1(A1g), ν2(Eg), ν5(F2g), and the overtone 2ν6 of SF6 have been investigated with a higher resolution and the band origins were estimated to be: ν1 = 774.53 cm−1, ν2 = 643.35 cm−1, ν5 = 523.5 cm−1, and 2ν6 = 693.8 cm−1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν6 fundamental frequency is calculated as 347.0 cm−1. From the analysis of the ν2 Raman band, the following rotational constants of both the ground and upper states have been calculated: B 0 = 0.09111 ± 0.00005 cm −1 ; D 0 = (0.16±0.08)10 −7 cm −1 ; B 2 = 0.09116 ± 0.00005 cm −1 ; D 2 = (0.18±0.04)10 −7 cm −1 . |
| Databáze: | OpenAIRE |
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