| Autor: | I. K. Marshakov, I. D. Zartsyn, A. E. Shugurov |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
Physics::Instrumentation and Detectors
Chemistry Organic Chemistry Inorganic chemistry Metals and Alloys Thermodynamics Kinetic energy Surfaces Coatings and Films Cathodic protection Anode Metal Physics::Plasma Physics Ionization visual_art Materials Chemistry visual_art.visual_art_medium Hydrogen evolution Dissolution Conjugate |
| Zdroj: | Protection of Metals. 37:138-143 |
| ISSN: | 0033-1732 |
| DOI: | 10.1023/a:1010369904266 |
| Popis: | Based on an idea about common intermediate particles, a physicochemical model of iron dissolution and hydrogen evolution is proposed. According to the model, the independence of the dissolution rate of a cathodically polarized metal of the potential is a particular case of chemically conjugate anodic–cathodic reactions. Parameters of the model calculated with the use of kinetic diagrams are compared with the experimental values. Assumptions which provide a satisfactory agreement between the calculated and experimental data are formulated. Equations describing the dissolution of iron both in the anodic and cathodic ranges are obtained. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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