Rate-structure studies of the carbonylation and decarbonylation of substituted metal carbonyl complexes
| Autor: | James N. Cawse, R. L. Pruett, R.A. Fiato |
|---|---|
| Rok vydání: | 1979 |
| Předmět: |
Organic Chemistry
Decarbonylation chemistry.chemical_element Metal carbonyl Manganese Photochemistry Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Insertion reaction Materials Chemistry Physical and Theoretical Chemistry Taft equation Carbonylation Ethylene glycol Carbon monoxide |
| Zdroj: | Journal of Organometallic Chemistry. 172:405-413 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)92313-1 |
| Popis: | The rate of CO insertion for the following complexes have been determined: RCH 2 Mn(CO) 5 where R cyclohexyl, hydrogen, phenyl, methoxy, and carboxyl; RCH 2 Fe(CO) 4 − where R cyclohexyl, n-octyl, n-heptyl, and phenyl. It appears that a Taft σϱ correlation can be established for this reaction. Rate data for the decarbonylation reaction of an analogous series of substituted manganese carbonyl complexes (RCH 2 COMn(CO) 5 ) was also obtained. As in the case of the CO insertion reaction, the rates increase as the Taft σ for RCH 2 decreases. The linear free energy relationships (LFER) generated in this study have been used to predict the relative probability of several reaction steps that have been postulated for the conversion of carbon monoxide and hydrogen into ethylene glycol. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|