Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads: Expanding the structural diversity of photoactive materials

Autor:	Alexander S. Konev, Dmitriy V. Androsov, Kaoru Yamanouchi, Alexey Povolotskiy, Daniil A. Lukyanov, Artem A. Strelnikov, Alexander F. Khlebnikov
Rok vydání:	2018
Předmět:	Fullerene 010405 organic chemistry Organic Chemistry Aziridine 010402 general chemistry Ring (chemistry) 01 natural sciences Biochemistry Combinatorial chemistry Porphyrin Cycloaddition 0104 chemical sciences chemistry.chemical_compound chemistry Phenylene Drug Discovery Linker Pyrrole
Zdroj:	Tetrahedron. 74:3007-3019
ISSN:	0040-4020
Popis:	A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::907dbf71672d208f5375eaf94b130d9d https://doi.org/10.1016/j.tet.2018.04.084 Zobrazit plný text záznamu Full Text from ScienceDirect