Repulsive KAr potentials from differential optical collisions
Autor: | Cristina Figl, J. Grosser, Frank Rebentrost, O. Hoffmann |
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Rok vydání: | 2004 |
Předmět: | |
Zdroj: | Journal of Physics B: Atomic, Molecular and Optical Physics. 37:3369-3377 |
ISSN: | 1361-6455 0953-4075 |
Popis: | Experimental differential cross sections for the optical collision process K(4s)2S + Ar + hν → K(4p)2P + Ar are reported. The characteristic interference structures are used to determine the repulsive parts of the KAr X2Σ and B2Σ potential curves by comparison with the results of exact quantum coupled-channel scattering calculations. By a least-squares procedure we obtain potentials with a relative accuracy of typically 1% in the range 0 ≤ V ≤ 1000–1500 cm−1, corresponding to absolute values of 2–4 cm−1 for the larger and 10–15 cm−1 for the smaller distances sampled by the experiment. |
Databáze: | OpenAIRE |
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