Metal–Organic Rotaxane Frameworks Assembly by Cucurbit[6]uril-Based Pseudorotaxanes and Mixed Ligands

Autor:	Yan-Qing Jiao, Zhong-Min Su, Xue-Song Wu, Xiao-Li Hu, Bai-Qiao Song, Xin-Long Wang, Jun Liang
Rok vydání:	2015
Předmět:	Rotaxane Chemistry Stereochemistry Building unit General Chemistry Condensed Matter Physics Fluorescence Metal chemistry.chemical_compound Crystallography visual_art visual_art.visual_art_medium General Materials Science Carboxylate Isostructural
Zdroj:	Crystal Growth & Design. 15:4311-4317
ISSN:	1528-7505 1528-7483
DOI:	10.1021/acs.cgd.5b00612
Popis:	Four novel high-dimensional metal–organic rotaxane frameworks (MORFs) were successfully fabricated by cucurbit[6]uril-based pseudorotaxanes ([PR43]) and rigid carboxylate ligands by adjusting the synthesis temperature and the length of ligands. Compound 1 represents a three periodic 2-fold interpenetrating dia network based on a binuclear {Cd2Cl4O4} second building unit (SBU). 2 and 3 are isostructural pcu networks constructed by binuclear and trinuclear cadmium clusters, respectively, while compound 4 is a two-dimensional layered network with a large grid 44.3 × 19.8 A2. Furthermore, their fluorescent properties in different solvents are investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::906f3d2fd2e7de8ff24992c68366dda6 https://doi.org/10.1021/acs.cgd.5b00612 Zobrazit plný text záznamu