Recent advances on N-heterocyclic carbene transition metal complexes for dehydrogenative catalysis using alcohols
| Autor: | Zhuofeng Ke, Cunyuan Zhao, Ming Huang, Xiao-Bing Lan, Peifeng Su, Jiahao Liu, Yinwu Li |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Chemistry
Alcohol 02 engineering and technology General Chemistry Bond formation 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Transition metal Polymer chemistry Dehydrogenation 0210 nano-technology Carbene |
| Zdroj: | Catalysis Today. 370:114-141 |
| ISSN: | 0920-5861 |
| Popis: | N-heterocyclic carbenes (NHCs) are green and versatile ligands for the development of transition metal (TM) catalysts. Presented is a brief overview of recent advances on NHC-TM complexes for dehydrogenative catalysis using alcohols. Various NHC-TM complexes, mostly based on noble metals Ir, Ru, and Os, as well as some non-noble metals like Cu, Mo, and Mn, are described. These NHC-TM complexes have been applied to acceptorless alcohol dehydrogenation (AAD) to aldehydes or ketones, and dehydrogenative coupling of alcohols for C O bond, C C bond, C N or C N bond formation. In comparison, the NHC-based Ru and Ir systems are relatively widely studied, the development of NHC-based non-noble metals catalysts is still in its infant for sustainable dehydrogenative catalysis using alcohols. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect