Synthesis of 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose a non-metabolisable analogue of sucrose

Autor:	Luigi Panza, Giovanni Russo, Francesco Nicotra, Marta Carcano
Rok vydání:	1989
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Sucrose Chemistry Ylide Stereochemistry Disaccharide Molecular Medicine Organic chemistry 1-deoxy-D-fructose
Zdroj:	J. Chem. Soc., Chem. Commun.. :642-643
ISSN:	0022-4936
DOI:	10.1039/c39890000642
Popis:	Reaction of the ylide (6), obtained from the known 1′-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)prop-2-ene (2), with 2,3-O-isopropylidene-D-glyceraldehyde, osmylation of the product (7), and deprotection, affords 1-(α-D-glucopyranosyl)-1-deoxy-D-fructose (1), a C-disaccharide structurally related to sucrose.
Databáze:	OpenAIRE
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