Tandem O-H Insertion/[3,3]-Sigmatropic Rearrangement of Rhodium Carbenoids with 2-Furfuryl Alcohols: A Strategy To Access Polysubstituted Furans

Autor:	Jinna Song, Rui Zhao, Hannan Wang, Pengbing Mi
Rok vydání:	2018
Předmět:	Tandem 010405 organic chemistry Organic Chemistry chemistry.chemical_element Sigmatropic reaction 010402 general chemistry 01 natural sciences 0104 chemical sciences Rhodium chemistry.chemical_compound chemistry Functional group Organic chemistry Organic synthesis Physical and Theoretical Chemistry
Zdroj:	European Journal of Organic Chemistry. 2018:759-762
ISSN:	1434-193X
DOI:	10.1002/ejoc.201701217
Popis:	Polysubstituted furans are versatile building blocks in organic synthesis and are widely spread over in variety of natural products, pharmaceuticals and functional materials. Herein, we report a convenient, facile and economic approach for the synthesis of polysubstituted furans through a tandem O−H insertion/[3,3]-sigmatropic rearrangement of rhodium carbenoids with easily available furfuryl alcohols. This protocol is characterized by its operational simplicity, high efficiency with excellent yields, broad substrate scope and greater functional group tolerance.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::90042de9f36a675eb2a1547deae7018d https://doi.org/10.1002/ejoc.201701217 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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