Petroleum-contaminated soil: using sonolysis to improve mineralization and biodegradation potential of Fenton reaction and ozonolysis process

Autor: Rafael Ariente-Neto, Renan C. Testolin, Cleder A. Somensi, Claudemir M. Radetski, Ramaiana Radetski-Silva, Albertina X.R. Corrêa, Eric Sanches-Simões, Gabriela T Schmidt, Wendell Pimentel-Almeida, Luciana Mater
Rok vydání: 2021
Předmět:
Zdroj: Environmental Science and Pollution Research. 28:16532-16543
ISSN: 1614-7499
0944-1344
Popis: The degradation efficiency of the Fenton reaction or ozonolysis (O3) to treat soil contaminated by crude petroleum was studied in association with the sonolysis process. To quantify oxidation efficiency, total organic carbon (TOC) and chemical oxygen demand (COD) were measured, while biochemical oxygen demand (BOD5) was measured to estimate biodegradation potential. TOC removal efficiency ranged from 9 to 52% to the Fenton reaction without sonolysis, and 18% and 78% with sonolysis for reagent concentrations of 1% H2O2-100 mM Fe2+ and 20% H2O2-1 mM Fe2+, respectively. For ozonolysis (after 10 and 60 min of treatment), the reduction in TOC ranged from 9 to 43% without sonolysis and 15 to 61% with sonolysis. The Fenton reaction without sonolysis increased the biodegradability in relation to the non-oxidized sample by 6% (1% H2O2-100 mM Fe2+) and 26% (20% H2O2-1 mM Fe2+), and with sonolysis the corresponding values were 13% and 42%, respectively. The biodegradation potential under ozonolysis without sonolysis increased from 0.18 (10 min of treatment) to 0.38 (30 min of treatment), and with sonolysis these values were 0.26 and 0.58, respectively. Optimization of the remediation processes is essential to determine sequential treatment order and efficiency.
Databáze: OpenAIRE
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