The first metal complex containing a silylated β-diketonate ligand: bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato) copper(II)
| Autor: | Rolf U. Claessen, Kulbinder K Banger, Alain E. Kaloyeros, Eric Eisenbraun, Andrei Kornilov, Paul J. Toscano, John T. Welch |
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| Rok vydání: | 2001 |
| Předmět: |
Silicon
Ligand Inorganic chemistry chemistry.chemical_element Crystal structure Chemical vapor deposition Copper Inorganic Chemistry Metal chemistry.chemical_compound Ultraviolet visible spectroscopy chemistry visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Homoleptic |
| Zdroj: | Inorganic Chemistry Communications. 4:496-500 |
| ISSN: | 1387-7003 |
| Popis: | A facile preparation of 2,2,6,6-tetramethyl-2-sila-3,5-heptanedione (tmshdH), exemplar of a new class of ligands, the sila-β-diketones, has been developed. Silicon substitution in the ligands has profound effects on the volatility, thermal properties, crystal packing, and electronic spectrum of the homoleptic Cu(II) complex, Cu(tmshd)2. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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