ChemInform Abstract: Electrified Microheterogeneous Catalysis in Low Ionic Strength Media

Autor: Debra R. Rolison, Joseph Z. Stemple
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 24
ISSN: 0931-7597
DOI: 10.1002/chin.199317056
Popis: The ability to drive catalytic processes when dc voltages are applied to low ionic strength dispersions has been demonstrated for the selective partial oxidation of propene at 0 °C in an aqueous dispersion of PdII–CuII supported on Y zeolite where the primary partial oxidation product can be either acetone or propylene oxide depending on the nature of the dispersed solid; in the absence of the applied electrifying force no product forms and in the absence of the molecular catalyst no selective oxidation occurs.
Databáze: OpenAIRE