ChemInform Abstract: Electrified Microheterogeneous Catalysis in Low Ionic Strength Media
Autor: | Debra R. Rolison, Joseph Z. Stemple |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 24 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199317056 |
Popis: | The ability to drive catalytic processes when dc voltages are applied to low ionic strength dispersions has been demonstrated for the selective partial oxidation of propene at 0 °C in an aqueous dispersion of PdII–CuII supported on Y zeolite where the primary partial oxidation product can be either acetone or propylene oxide depending on the nature of the dispersed solid; in the absence of the applied electrifying force no product forms and in the absence of the molecular catalyst no selective oxidation occurs. |
Databáze: | OpenAIRE |
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