α-Unsubstituted γ,δ-Unsaturated Aldehydes by Claisen Rearrangement: 3-Phenyl-4-pentenal

Autor:	George Büchi, Dennis E. Vogel
Rok vydání:	2003
Předmět:	Claisen rearrangement chemistry.chemical_compound Hydrolysis Betaine chemistry Decarboxylation Halogen Organic chemistry Ammonium Medicinal chemistry Tetrahydrofuran Acrylic acid
Zdroj:	Organic Syntheses
DOI:	10.1002/0471264180.os066.05
Popis:	α-Unsubstituted γ,δ-unsaturated aldehydes by Claisen rearrangement: 3-phenyl-4-pentenal intermediate: (E)-(carboxyvinyl)trimethylammonium betaine intermediate: (E)-3-[(E)-3-phenyl-2-propenoxy]acrylic acid product: 3-phenyl-4-pentenal Keywords: addition, to CC; decarboxylation; hydrolysis, esters and lactones; rearrangements; replacement reactions, ammonium by oxygen; replacement reactions, hydroxy by halogen; tetrahydrofuran
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8fe58d80d3ce7776e1e553d407ffda93 https://doi.org/10.1002/0471264180.os066.05 Zobrazit plný text záznamu