Blends of etheric polyitaconates and polyacrylates with acidic polymers

Autor:	Bradley K. Coltrain, David M. Teegarden, Christine J. T. Landry, Wayne T. Ferrar
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Polymers and Plastics Hydrogen bond Methacrylate copolymer Organic Chemistry Mixing (process engineering) Polymer Miscibility Styrene Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Copolymer Side chain
Zdroj:	Macromolecules. 26:5543-5551
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma00073a003
Popis:	The miscibility between polyitaconates [CH 2 C(COOR)(CH 2 COOR)] x [CH 2 C(COOH)(CH 2 COOR)] y (R= (CH 2 CH 2 O) m CH 3 m= 2,3; x=0.7 y= 0.3; x=1 y= 0) and polyacrylates [CH 2 C(Me)(CO[OCH 2 CH 2 ] 2 OCH 3 )] n and polymers bearing an acidic functionality, such as poly(vinylphenol) (PVPh) and its copolymers with styrene, and poly(styrene-co-styrene-4-sulfonic acid), is investigated. Heats of mixing measurements are performed on model compounds of these polymers, revealing that the interactions are dominated by the etheric side chains, even though the polyitaconates also contain carbonyl groups that are good hydrogen bond acceptors
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8fc407d43a0f8a728550593b4caedf6c https://doi.org/10.1021/ma00073a003 Zobrazit plný text záznamu