Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance
| Autor: | Xiao-Hong Wang, Jie Huang, Xiaojing Hang, Fan Shang, Xiao Ma, Zimei Ding |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Exothermic process Detonation velocity Thermal decomposition Analytical chemistry Detonation chemistry.chemical_element 02 engineering and technology General Chemistry Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Furazan 01 natural sciences Nitrogen 0104 chemical sciences chemistry.chemical_compound chemistry 0210 nano-technology Single crystal |
| Zdroj: | Chemical Research in Chinese Universities. 35:848-853 |
| ISSN: | 2210-3171 1005-9040 |
| DOI: | 10.1007/s40242-019-9138-x |
| Popis: | The structure of 4-amino-3-(5-tetrazolate)-furazan(HAFT) was characterized by single crystal X-ray diffraction. The thermal decomposition process of HAFT was investigated by MS-FTIR-DSC-TG coupling technique. The result shows that the exothermic process occurs from 278.7―350 °C, with a peak temperature of 324.7 °C. The thermal decomposition gaseous products of HAFT are NO2, CO2, HCN, CO, NH3 and H2O. The detonation velocity and detonation pressure of HAFT were calculated by the nitrogen equivalent equation. The detonation velocity of HAFT is 7727.46 m/s, which is higher than that of TNT(7178 m/s). The detonation pressure of HAFT(25.27 GPa) is satisfactory. The sensitivity tests reveal HAFT possesses excellent insensitivities to impact and friction. |
| Databáze: | OpenAIRE |
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