[C6F5Xe]+ as potential source of the electrophilic [C6F5] radical

Autor:	H.J. Frohn, A. Klose
Rok vydání:	1992
Předmět:	CIDNP Chemistry Organic Chemistry Thermal decomposition Photochemistry Biochemistry Oxidative addition Radical cyclization Inorganic Chemistry Solvent NMR spectra database Electrophile Environmental Chemistry Potential source Physical and Theoretical Chemistry
Zdroj:	Journal of Fluorine Chemistry. 58:274
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(00)80729-0
Popis:	Thermal decomposition of [C 6 F 5 Xe] + salts with complex fluoroanions can proceed in two different ways: a crypto-ionic and/or a radical path, depending on temperature and solvent. The intermediate formation of long-lived radical pairs could be established by observation of the CIDNP effect in 19 F NMR spectra. Oxidative addition reactions of [C 6 F 5 Xe] + on organoelement compounds can proceed via a crypto-ionic and/or radical path. Examples of both reaction patterns are presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8f538a1aa2f64aad0f9e716a99937853 https://doi.org/10.1016/s0022-1139(00)80729-0 Zobrazit plný text záznamu