Kinetic analysis of a single-path, and of a dual-path, sequence of four first-order reactions. The reactions of dibenzoylmesitylene and acetylbenzoylmesitylene in sulfuric acid

Autor:	Gerald F. Moxon, David N. Waters, Jameel A. Farooqi, Peter H. Gore
Rok vydání:	1988
Předmět:	Chemistry Organic Chemistry Kinetic analysis Sulfuric acid First order Kinetic energy Biochemistry Inorganic Chemistry chemistry.chemical_compound Computational chemistry Path (graph theory) Organic chemistry Physical and Theoretical Chemistry Sequence (medicine)
Zdroj:	International Journal of Chemical Kinetics. 20:95-102
ISSN:	1097-4601 0538-8066
DOI:	10.1002/kin.550200202
Popis:	Dibenzoylmesitylene undergoes protiodeacylation in 89.8% (w/w) sulfuric acid at ca. 90°C, with subsequent sulfonation, to give mesitylenedisulfonic acid. The reaction involves a single-path sequence of four first-order reactions. The corresponding reaction of acetylbenzoylmesitylene can proceed by two possible routes: it is shown that about 94% of the overall reaction at 75° involves initial protiodeacetylation and about 6% initial protiodebenzoylation. The kinetic analyses provide estimates of concentration ratios as functions of time, and of the buildup and decay of intermediates in the reactions.
Databáze:	OpenAIRE
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