Nmr investigation of nickel(II) scriff base complexes with benzoyl substituents
| Autor: | Setsuko Kinoshita, Hisanobu Wakita, Manabu Fujiwara, Yoshihide Ichiki |
|---|---|
| Rok vydání: | 1991 |
| Předmět: |
chemistry.chemical_classification
Schiff base Base (chemistry) Stereochemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Carbon-13 NMR Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Nickel chemistry Materials Chemistry Molecule Chelation Physical and Theoretical Chemistry |
| Zdroj: | Polyhedron. 10:2833-2838 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/s0277-5387(00)86187-2 |
| Popis: | The nickel(II) Schiff base complexes with isobutyl chains and benzoyl substituents have been prepared and characterized by 1H and 13C NMR spectroscopies. In the complex, the donor set of N2O2 has a square planar coordination, the benzoyl substituents are perpendicular to the chelate plane and the isobutyl groups move segmentally so that they may approach the benzoyl substituents. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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