Single-Crystal-to-Single-Crystal Breathing and Guest Exchange in CoII Metal–Organic Frameworks
| Autor: | Parthasarathi Dastidar, Sumi Ganguly, Sandip Mukherjee |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Ligand
02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Crystallography chemistry.chemical_compound chemistry Acetone Organic chemistry General Materials Science Metal-organic framework 0210 nano-technology Benzamide Single crystal |
| Zdroj: | Crystal Growth & Design. 16:5247-5259 |
| ISSN: | 1528-7505 1528-7483 |
| Popis: | Single-crystal-to-single-crystal (SCSC) breathing and guest exchange properties of a series of CoII metal–organic frameworks (MOFs) are reported. A new bis-pyridyl-bis-amide ligand, namely 4,4′-oxybis(N-(pyridine-4-yl)benzamide) (LP1), produced two MOFs, namely [{Co(LP1)(IPA)}(DMF)2(H2O)]∞ (1) and [{Co2(LP1)2(TPA)2}(DMF)4]∞ (2) under solvothermal conditions (IPA = isophthalate, TPA = terephthlate). While 1 showed excellent SCSC breathing responsive to both heat and guests (acetone, DMSO, MeOH, DEF), 2 displayed no breathing under similar conditions. However, it showed excellent SCSC guest (acetone, DMSO) exchange properties. Single-crystal structural analyses revealed that the conformational flexibility of the ligand LP1 played a crucial role both in breathing in 1 and in guest exchange in 2. Compound 1 also displayed heat responsive magnetic changes. |
| Databáze: | OpenAIRE |
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