Vibrational spectra and normal vibrations of bis(salicylaldoximato) nickel(II) and pailadium(II)

Autor:	Italo Pellegrini, Adriano Bigotto
Rok vydání:	1984
Předmět:	chemistry.chemical_classification Infrared Inorganic chemistry General Engineering Analytical chemistry chemistry.chemical_element Dichroism Polarization (waves) Spectral line symbols.namesake Nickel chemistry symbols Raman spectroscopy Single crystal Inorganic compound
Zdroj:	Spectrochimica Acta Part A: Molecular Spectroscopy. 40:979-990
ISSN:	0584-8539
DOI:	10.1016/0584-8539(84)80157-9
Popis:	The i.r. spectra of Ni(II) and Pd(II)-bissalicylaldoximates have been measured from 4000 to 200 cm − : polarized spectra of single crystals have been also obtained. The Raman spectra of the complexes as polycrystalline samples and in solution have been investigated and the polarization of several lines has been determined. A detailed assignment of most of the observed bands has been proposed on the basis of the i.r. dichroism, Raman polarization data and correlative criteria. A normal coordinate treatment has been carried out for the in-plane modes in order to clarify the assignments quantitatively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8ef092269f6538bcc25b144b2af02de1 https://doi.org/10.1016/0584-8539(84)80157-9 Zobrazit plný text záznamu