'Dormant' inhibitors of urethane type as controllers of temperature modes of styrene polymerization

Autor:	A. L. Aleksandrov, Ya. S. Estrin, A. S. Dzhalmukhanova, V. V. Komratova, Vera P. Lodygina, A. I. Kuzaev, G. A. Gorbushina, Elmira R. Badamshina, T. N. Fedotova, I. S. Kochneva, A. A. Grishchuk, E. V. Stovbun
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Monomer Bulk polymerization chemistry Polymerization General Chemical Engineering Polymer chemistry Radical polymerization Organic chemistry General Chemistry Emergency situations Isocyanate Styrene
Zdroj:	Russian Journal of Applied Chemistry. 81:1821-1830
ISSN:	1608-3296 1070-4272
DOI:	10.1134/s1070427208100224
Popis:	Urethanes based on a series of monoisocyanates and phenolic inhibitors of styrene radical polymerization, which release the initial phenolic inhibitor at elevated temperatures, were prepared and characterized. Some of these compounds meet the requirements to “dormant” inhibitors: they sharply decelerate thermally initiated high-temperature polymerization of styrene and do not noticeably affect the rate of low-temperature polymerization in the presence of an inhibiting substance. The possibility of preventing uncontrollable emergency situations by adding these compounds to the initial monomer was confirmed experimentally.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8ea19f92a99b4a032a33852a88bb0f97 https://doi.org/10.1134/s1070427208100224 Zobrazit plný text záznamu Full text from SpringerLink