Synthesis of redox-active donor/acceptor chromophores with a central indenofluorene or indacenodithiophene core

Autor:	David Bo Nygaard, Mogens Brøndsted Nielsen, Rasmus Refsgaard Kragh, Line Broløs, Dianna Andersen
Rok vydání:	2020
Předmět:	010405 organic chemistry Chemistry Organic Chemistry Chromophore 010402 general chemistry 01 natural sciences Biochemistry Tetracyanoquinodimethane Redox 0104 chemical sciences chemistry.chemical_compound Drug Discovery Polymer chemistry Redox active Molecule Donor acceptor Tetrathiafulvalene
Zdroj:	Tetrahedron Letters. 61:151939
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2020.151939
Popis:	Tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ) are classical redox-active molecules that can be oxidized and reduced, respectively, in two one-electron steps. Herein we present the synthesis of a selection of extended derivatives based on either an indenofluorene or indacenodithiophene core and containing either two dithiafulvene units (extended TTF), two dicyanomethylene units (extended TCNQ) or one of each of these units (donor–acceptor system). The optical and redox properties of the molecules are also presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8e88b87f01e18822f479d7a1274c1f52 https://doi.org/10.1016/j.tetlet.2020.151939 Zobrazit plný text záznamu Full Text from ScienceDirect