Chemical synthesis and characterization of soluble poly(4,4′-dialkyl-2,2′-bithiophenes)
| Autor: | Malgorzata Zagorska, Bernd Krische |
|---|---|
| Rok vydání: | 1990 |
| Předmět: |
chemistry.chemical_classification
Chloroform Polymers and Plastics Organic Chemistry Solution polymerization Polymer Nuclear magnetic resonance spectroscopy Electrochemistry Chemical synthesis chemistry.chemical_compound chemistry Polymerization Materials Chemistry Organic chemistry Cyclic voltammetry |
| Zdroj: | Polymer. 31:1379-1383 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/0032-3861(90)90234-p |
| Popis: | Chemical polymerization of 4,4′-dialkyl-2,2′-bithiophenes is reported. The resulting soluble polymers can be cast from their chloroform solutions to give thin layers and free-standing films, which can be doped by electrochemical and chemical methods. Cyclic voltammetry and 1 H nuclear magnetic resonance spectroscopy give evidence of better stereoregularity of the polymers obtained from disubstituted bithiophenes as compared to those obtained from 3-substituted thiophenes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|