Synthesis ofrac-(E)-Opposita-4(15),7(11)-dien-12-al
Autor: | Helga Marschall, Peter Weyerstahl, Peter Degenkolb, Philippine Lebada |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | European Journal of Organic Chemistry. 1999:675-678 |
ISSN: | 1099-0690 1434-193X |
DOI: | 10.1002/(sici)1099-0690(199903)1999:3<675::aid-ejoc675>3.0.co;2-b |
Popis: | rac-(E)-Opposita-4(15),7(11)-dien-12-al (1) was synthesized in 12 steps via the aldehyde 11 as the key compound. The spectroscopic data of rac-1 are identical with those of the corresponding natural product, previously isolated from Vetiver oil. Synthetic rac-1 has a strong, green woody odor with soft-floral undertones, which confirms that 1 is an olfactorily important constituent of Vetiver oil. |
Databáze: | OpenAIRE |
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