Synthesis ofrac-(E)-Opposita-4(15),7(11)-dien-12-al

Autor: Helga Marschall, Peter Weyerstahl, Peter Degenkolb, Philippine Lebada
Rok vydání: 1999
Předmět:
Zdroj: European Journal of Organic Chemistry. 1999:675-678
ISSN: 1099-0690
1434-193X
DOI: 10.1002/(sici)1099-0690(199903)1999:3<675::aid-ejoc675>3.0.co;2-b
Popis: rac-(E)-Opposita-4(15),7(11)-dien-12-al (1) was synthesized in 12 steps via the aldehyde 11 as the key compound. The spectroscopic data of rac-1 are identical with those of the corresponding natural product, previously isolated from Vetiver oil. Synthetic rac-1 has a strong, green woody odor with soft-floral undertones, which confirms that 1 is an olfactorily important constituent of Vetiver oil.
Databáze: OpenAIRE