Electrochemical reduction of arsine oxides in dimethylformamide

Autor:	B. D. Chernokal'skii, A. S. Gel'fond, N. I. Semakhina, Yu. M. Kargin, G. Kh. Kamai
Rok vydání:	1970
Předmět:	chemistry.chemical_compound Arsine chemistry Chemical bond Inorganic chemistry Atom Electrophile Dimethylformamide Phenol Molecule General Chemistry Electrochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 19:2341-2345
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00859072
Popis:	1. Oxides of triphenyl- and aryldiethylarsines in dimethylformamide are reduced in one irreversible two-electron step. In the presence of phenol, four or more electrons per molecule are consumed for the reduction. 2. The satisfactory correlation of the half-wave potentials with the Hammett and electrophilic constants of the substituents in the series of aryldiethylarsine oxides is considered as evidence of the participation of the d-orbitals of the As atom in the formation of chemical bonds. 3. The Hammett and electrophilic constants of the p-As(O)Et2 and p-AsEt2 groups were found.
Databáze:	OpenAIRE
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