Distribution of water and of caprolactam between vapor and polymer phases in the solid-phase synthesis of polycaproamide
| Autor: | S. Yu. Pashkova, L. N. Mizerovskii, D. L. Siganov |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Range (particle radiation) Materials science General Chemical Engineering Vapor phase Evaporation Analytical chemistry Caprolactam General Chemistry Polymer chemistry.chemical_compound Solid-phase synthesis chemistry Volume (thermodynamics) Polymer chemistry General Materials Science Ton |
| Zdroj: | Fibre Chemistry. 23:256-259 |
| ISSN: | 1573-8493 0015-0541 |
| DOI: | 10.1007/bf00552632 |
| Popis: | Distribution constants of water and CL between the vapor phase and solid PCA at 413–463 K have been determined. -- Results of calculations have been given which show that the stage of solid-phase final amidation of PCA can be realized in apparatus which ensures maintaining the pressure in the range 1.1–1.5 MPa; thereupon, the losses of CL because of evaporation into the free volume of the apparatus do not exceed 9 kg per ton of polymer. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink