Metallo-porphyrazines with eight [5-thiopentyl 3,4,5-tris(benzyloxy)benzoate] groups: Synthesis, characterization, aggregation, and solubility behavior
| Autor: | Ergün Gonca |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Pyrazine
010405 organic chemistry Organic Chemistry Porphyrazine Carbon-13 NMR 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Pyridine Proton NMR Organic chemistry Reactivity (chemistry) Solubility Spectroscopy Benzoic acid |
| Zdroj: | Journal of Molecular Structure. 1130:10-18 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2016.09.073 |
| Popis: | Metal-free and metallo-porphyrazines having eight 5-hydroxypentylthio units at the peripheral positions have been prepared from 2,3-bis(5-hydroxypentylthio)maleonitrile. By the esterification reaction of magnesium hydroxy-porphyrazine with 3,4,5-tris(benzyloxy)benzoic acid in dicyclohexylcarbodiimide and toluene-p-sulfonic acid, the reactivity of the hydroxypentyl units was indicated. On the other hand, iron porphyrazine derivatives with eight [5-thiopentyl 3,4,5-tris(benzyloxy)benzoate] groups attached to the periphery positions were synthesized. By the reaction of metal-free porphyrazine with iron (II) acetate and further processing with HCl solution, FePzCl was obtained. Finally, by reacting FePzCl with pyridine or pyrazine, [FePz(py)2] and [FePz(pyz)]n complexes were prepared, respectively. The characterizations of target complexes were carried out by utilizing different spectroscopic methods such as FT-IR, UV–vis, mass, 1H NMR, and 13C NMR together with elemental analysis. |
| Databáze: | OpenAIRE |
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