Spectroscopic studies on molecular vanadium pentafluoride isolated in inert gas matrices

Autor:	Eric G. Hope
Rok vydání:	1990
Předmět:	Infrared Inorganic chemistry chemistry.chemical_element General Chemistry Nitrogen Spectral line chemistry.chemical_compound Trigonal bipyramidal molecular geometry Matrix (mathematics) Monomer chemistry Physical chemistry Vanadium pentafluoride Inert gas
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :723
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9900000723
Popis:	Matrix-isolation studies have been carried out on vanadium pentafluoride. In a nitrogen matrix prominent i.r. bands at 806 and 769 cm–1 are assigned to V–F stretching modes of monomeric VF5(D3h). Corresponding u.v.–visible spectra were obtained and assigned on the basis of trigonal bipyramidal geometry.
Databáze:	OpenAIRE
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