Stereoisomers of an azine-linked donor–acceptor conjugated polymer: the impact of molecular conformation on electrical performance
| Autor: | M. Carmen Ruiz Delgado, Iratxe Arrechea-Marcos, Taiho Park, Mithrabinda K. Poduval, Rocío Ponce Ortiz, J. Teodomiro López Navarrete, Tae-Hyun Kim |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
General Chemical Engineering chemistry.chemical_element 02 engineering and technology General Chemistry Polymer Conjugated system 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Acceptor 0104 chemical sciences Azine chemistry.chemical_compound chemistry Polymer chemistry Lactam Molecule Linkage isomerism 0210 nano-technology Palladium |
| Zdroj: | RSC Advances. 6:44272-44278 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c6ra07389a |
| Popis: | We herein report the synthesis of a pair of azine linked donor–acceptor type conjugated polymers by the use of palladium(II)-based direct arylation. The two stereoisomers of the azine molecule were synthesized, separated, characterized, and further incorporated with a thiophene–phenylene–thiophene-based fused lactam (TPTL) acceptor molecule to form the donor–acceptor skeletons. The effects of the azine linkage isomerism on the polymer skeleton were studied both theoretically and experimentally. Semiconducting properties of these polymers were also evaluated in thin film transistors. |
| Databáze: | OpenAIRE |
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