ChemInform Abstract: A Novel, Chemoselective One-Pot Procedure for the Preparation of 3H-Spiro[isobenzofuran-1,2′-pyrrole]-3,3′(1′H)-dione Derivatives via Oxidative Cleavage of 3a,8b-Dihydroxyindeno[1,2-b]pyrroles

Autor:	Noushin Ariapour, Mohammad Reza Mohammadizadeh, Gholam Hossein Mahdavinia, Maryam Alborz
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Ethanol chemistry Isobenzofuran Ninhydrin Organic chemistry General Medicine Oxidative cleavage Redox Combinatorial chemistry Pyrrole
Zdroj:	ChemInform. 45
ISSN:	0931-7597
DOI:	10.1002/chin.201435116
Popis:	A one-pot, efficient and chemoselective procedure for the synthesis of new 3H-spiro[isobenzofuran-1,2′-pyrrole]-3,3′(1′H)-dione derivatives has been developed which involves room temperature oxidative cleavage of 3a,8b-dihydroxyindeno[1,2-b]pyrroles themselves synthesized from the reaction of ninhydrin and enaminones in 30% ethanol. A reasonable mechanism is proposed for the oxidation reaction based on the results of this study and our previous related work.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8d95890c800c09fdcda3caa7f507f9cf https://doi.org/10.1002/chin.201435116 Zobrazit plný text záznamu Plný text