Phosphatidic acids and derivatives: IV). Synthesis of α-glycerophosphatidic acids, starting from glycerol-α-iodohydrin

Autor: A. R. Todd, L. W. Hessel, P. E. Verkade, I. D. Morton
Rok vydání: 2010
Předmět:
Zdroj: Recueil des Travaux Chimiques des Pays-Bas. 73:150-156
ISSN: 0165-0513
DOI: 10.1002/recl.19540730211
Popis: Diacylglycerol-α-iodohydrins react smoothly with silver dibenzyl phosphate in the presence of benzene, with the formation of diacylglycerol-α-phosphoric acid dibenzyl esters. Upon hydrogenolysis in alcoholic suspension or solution in the presence of a palladium/active carbon catalyst the latter substances yield the corresponding diacylglycerol-α-phosphoric acids and toluene.
Databáze: OpenAIRE