Photolysis of 1,2-dibromo 3-chloro propane in water
| Autor: | C. Bernat-Escallon, J.C. Milano, J.L. Vernet |
|---|---|
| Rok vydání: | 1990 |
| Předmět: |
Environmental Engineering
Ecological Modeling Inorganic chemistry Photochemistry Pollution Propene Propanol chemistry.chemical_compound chemistry Propane Acetone Methanol Hydrogen peroxide Aliphatic compound Photodegradation Waste Management and Disposal Water Science and Technology Civil and Structural Engineering |
| Zdroj: | Water Research. 24:557-564 |
| ISSN: | 0043-1354 |
| DOI: | 10.1016/0043-1354(90)90187-b |
| Popis: | We have studied the photolysis of 1,2-dibromo 3-chloro propane dissolved to traces in water, in the possible presence of hydrogen peroxide. This compound accelerates the photodegradation kinetic velocity. In pure water and water containing hydrogen peroxide, the principal photoproducts, identified by gaseous phase chromatography coupled with mass spectrometry, are the same: 1-bromo 3-chloro 2-propanone, 2-bromo 3-chloro propanol, 1-bromo 3-chloro 2-propanol, 1-chloro 2-propanone, 3-bromo 1-chloro propene (Z and E), acetone and methanol. Hydrogen peroxide addition does not influence appreciably the nature of the photoproducts formed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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