Single-wall carbon nanotubes encaging linear chain C10H2 polyyne molecules inside

Autor: Makoto Sakata, Satoshi Kikuchi, Daisuke Nishide, Eiji Nishibori, Tomonari Wakabayashi, Hisanori Shinohara, Ryo Kitaura, Masashi Ishida, Shinobu Aoyagi, Hirofumi Dohi, Toshiki Sugai
Rok vydání: 2006
Předmět:
Zdroj: Chemical Physics Letters. 428:356-360
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2006.07.016
Popis: A new hybrid material C10H2@SWNTs, single-wall carbon nanotubes (SWNTs) encapsulating C10H2 polyyne molecules, has been synthesized and confirmed by Raman spectroscopy and X-ray diffraction measurement. The C10H2 polyyne molecules composed of linearly bonded sp-carbon atoms are aligned inside the SWNTs. This hybrid material exhibits a characteristic Raman signal at 2066 cm−1 attributable to the stretching vibration of the C10H2 molecules interacting with SWNTs. Being trapped inside the SWNTs, the otherwise unstable C10H2 molecules are shown to be stable well above 300 °C under dry-air conditions.
Databáze: OpenAIRE