Crystal and molecular structure of chloro-1,2-bis(diphenylphosphino)-ethanemonocarbonyl-π-cyclopentadienylmolybdenum(II)

Autor:	R. H. Fenn, J. H. Cross
Rok vydání:	1970
Předmět:	Ligand Stereochemistry chemistry.chemical_element Atom (order theory) Bridging ligand Ring (chemistry) Inorganic Chemistry Crystal Crystallography chemistry Cyclopentadienyl complex Molybdenum Molecule Physical and Theoretical Chemistry
Zdroj:	J. Chem. Soc. A. :3019-3022
ISSN:	0022-4944
Popis:	Chloro-1,2-bis(diphenylphosphino)ethanemonocarbonyl-π-cyclopentadienylmolybdenum(II), Mo(π-C6H5)(CO)-(Ph2PCH2)2CI, crystallizes in the space group Pbca(D2h15, No. 61), Z= 8, with cell dimensions a= 1·7395 ± 0·0007, b= 2·3744 ± 0·0008, c= 1·3792 ± 0·0019 nm. Data were collected photographically, and 2544 observed reflections were used to solve the structure by the heavy atom method (R= 7·47%). The molecule is of the sandwich type, with the cyclopentadienyl ring on one side of the molybdenum atom and the other ligands on the other side, and the carbonyl ligand is cis to the chlorine atom. The phosphorus ligand is bonded to a single molybdenum atom, and is not a bridging ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8d548d16362f41ff736bf01e6b92632b https://doi.org/10.1039/j19700003019 Zobrazit plný text záznamu